Carbonyl‐olefin metathesis reactions have emerged as an invaluable strategy for the direct formation of carbon–carbon bonds, enabling the efficient construction of complex molecular architectures.
Scientists at Scripps Research have used rapid alternating current (AC) to selectively reduce carbonyl groups (J. Am. Chem. Soc. 2021, DOI: 10.1021/jacs.1c06572). The technique avoids side reactions ...
Chiral tetrahydro-β-carbolines or tryptolines that contain a tetrasubstituted carbon center provides a framework for a variety of biologically active compounds. This basic structure is found in ...
Putting a new twist on an old favorite of organic chemistry, researchers have unveiled the phospha-bora-Wittig reaction. It offers a relatively straightforward way to prepare phosphaalkenes, which are ...