Complete the mechanism for the following Stork enamine acylation by drawing curved arrows, atoms,bonds, charges, and nonbonding electrons where indicated.a) Add curved arrows for this carbonbond formation.b) Add curved arrows to show the collapseof the tetrahedral intermediate.c) Draw the hydrolysis products.hydrolysis H2O-HCI
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Complete the mechanism for the following Stork enamine acylation by drawing curved arrows, atoms,bonds, charges, and nonbonding electrons where indicated.a) Add curved
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23-64 The Stork enamine reaction and the intramolecular aldol reaction canbe carried out in sequence to allow the synthesis of cyclohexenones.For example, reaction of the pyrrolidine enamine of cyclohexanonewith 3-buten-2-one, followed by enamine hydrolysis and base treat-ment, yields the product indicated. Write each step, and show themechanism of each.
23-64 The Stork enamine reaction and the intramolecular aldol reaction canbe carried out in sequence to allow the synthesis of cyclohexenones.For example, reaction of the pyrrolidine enamine of cyclohexanonewith 3-buten-2-one, followed by enamine hydrolysis and base treat-ment, yields the product indicated. Write each step, and show themechanism of each.
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